{"id":64198,"date":"2023-12-16T13:38:38","date_gmt":"2023-12-16T08:08:38","guid":{"rendered":"https:\/\/pwonlyias.com\/stage\/?post_type=ncert-notes&#038;p=64198"},"modified":"2024-09-26T12:42:30","modified_gmt":"2024-09-26T07:12:30","slug":"atomic-structure","status":"publish","type":"ncert-notes","link":"https:\/\/pwonlyias.com\/stage\/ncert-notes\/atomic-structure","title":{"rendered":"Atomic Structure: Protons, Neutrons and Electron Orbits"},"content":{"rendered":"<h2><span style=\"font-size: 24pt;\"><b>Basic Elements of Atomic Structure in the Structure of Matter:<\/b><\/span><\/h2>\n<p><span style=\"font-weight: 400;\">An atom is the fundamental unit of matter, consisting of a <\/span><b>nucleus composed of protons and neutrons, surrounded by electrons in orbit<\/b><span style=\"font-weight: 400;\">.The study of atoms is fundamental to chemistry and physics, providing insights into the structure, behavior, and interactions that govern the properties of matter, particularly the intricate details of atomic structure.<\/span><\/p>\n<p><span style=\"font-size: 18pt;\"><b>Atoms: Fundamental Building Blocks of our world:<\/b><\/span><\/p>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Atoms are the fundamental building blocks of all matter.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">The existence of different kinds of matter is due to different atoms constituting them.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Our entire world is made up of atoms.\u00a0<\/span><\/li>\n<\/ul>\n<h2><span style=\"font-size: 18pt;\"><b>What Does Atomic structure mean in Nanometer dimensions?<\/b><\/span><\/h2>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">Atoms are very small, they are smaller than anything that we can imagine or compare with in the realm of atomic structure.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Radius: <\/b><span style=\"font-weight: 400;\">Atomic radius is measured in nanometers.<\/span><\/li>\n<\/ul>\n<p style=\"padding-left: 40px;\"><span style=\"font-weight: 400;\">1\/1<\/span><span style=\"font-weight: 400;\">0<\/span><span style=\"font-weight: 400;\">9<\/span><span style=\"font-weight: 400;\">m = 1 nm<\/span><span style=\"font-weight: 400;\">\u00a0<\/span><\/p>\n<p style=\"padding-left: 40px;\"><span style=\"font-weight: 400;\">1m = 1<\/span><span style=\"font-weight: 400;\">0<\/span><span style=\"font-weight: 400;\">9\u00a0 <\/span><span style=\"font-weight: 400;\">nm<\/span><\/p>\n<figure id=\"attachment_64200\" aria-describedby=\"caption-attachment-64200\" style=\"width: 489px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-64200\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/a-2.webp\" alt=\"Thomson\u2019s model\" width=\"489\" height=\"271\" srcset=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/a-2.webp 489w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/a-2-300x166.webp 300w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/a-2-360x200.webp 360w\" sizes=\"(max-width: 489px) 100vw, 489px\" \/><figcaption id=\"caption-attachment-64200\" class=\"wp-caption-text\">Thomson\u2019s model of an atom<\/figcaption><\/figure>\n<h1><span style=\"font-size: 18pt;\"><b>How did the Discovery of Electrons and Protons shape Atomic Structure?<\/b><\/span><\/h1>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><span style=\"font-weight: 400;\">The discovery of two fundamental particles (electrons and protons) inside the atom, led to the failure of Dalton\u2019s atomic theory.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Various Models: <\/b><span style=\"font-weight: 400;\">Many scientists proposed various atomic models to explain how electrons and protons are arranged within an atom, emphasizing the intricate nature of atomic structure.<\/span><\/li>\n<\/ul>\n <div class=\"vc_gray_box\">\n                   <p> <\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-64203\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T130452.795.webp\" alt=\"J.J. Thomson\" width=\"232\" height=\"325\" srcset=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T130452.795.webp 232w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T130452.795-214x300.webp 214w\" sizes=\"(max-width: 232px) 100vw, 232px\" \/><\/p>\n<p style=\"text-align: center;\"><b>J.J. Thomson (1856-1940)<\/b><\/p>\n<p><span style=\"font-weight: 400;\">A British physicist, was born in Cheetham Hill, a suburb of Manchester, on 18 December 1856. He was awarded the Nobel prize in Physics in 1906 for his work on the discovery of electrons. He directed the Cavendish Laboratory at Cambridge for 35 years and seven of his research assistants subsequently won Nobel prizes.<\/span><\/p>\n<p> <\/p>\n                <\/div>\n<h2><span style=\"font-size: 18pt;\"><b>Thomson Pudding Model and the Foundations of Atomic Structure<\/b><\/span><\/h2>\n<ul>\n<li><b>Pudding Model and the Atomic Structure Analogy: <\/b><span style=\"font-weight: 400;\">Thomson proposed the model of an atom to be similar to that of a <\/span><b>Christmas pudding.<\/b><span style=\"font-weight: 400;\">\u00a0<\/span>\n<ul>\n<li><span style=\"font-weight: 400;\">The electrons, in a sphere of positive charge, were like currants (dry fruits) in a spherical Christmas pudding,\u00a0 illustrating the distribution within the atomic structure.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li><b>Thomson&#8217;s Atomic Proposal: Balanced charges and electric neutrality of the Atom<\/b><span style=\"font-weight: 400;\">: An atom consists of a positively charged sphere and the electrons are embedded in it.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">The negative and positive charges are equal in magnitude.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">So, the atom as a whole is electrically neutral.\u00a0<\/span><\/li>\n<\/ul>\n<h2><span style=\"font-size: 18pt;\"><b>Rutherford\u2019s Model of an Atom: Nucleus and Electron Paths in Atomic Structure:<\/b><\/span><\/h2>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Rutherford&#8217;s Electron Experiment: Atomic Arrangement:<\/b><span style=\"font-weight: 400;\"> Ernest Rutherford designed an experiment to know the arrangement of electrons within the atom.\u00a0<\/span><\/li>\n<\/ul>\n <div class=\"vc_gray_box\">\n                   <p> <\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-64237\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T132617.549-1.webp\" alt=\"E. Rutherford (1871-1937)\" width=\"144\" height=\"180\" \/><\/p>\n<p style=\"text-align: center;\"><b style=\"font-family: var(--list--font-family); background-color: var(--global--color-background); color: var(--global--color-primary); font-size: var(--global--font-size-base);\">Rutherford (1871-1937)\u00a0<\/b><\/p>\n<p><span style=\"font-weight: 400;\">He was born at Spring Grove on 30 August 1871. He was known as the <\/span><b>\u2018Father\u2019 of nuclear physics<\/b><span style=\"font-weight: 400;\">. He is famous for his work on radioactivity and the discovery of the nucleus of an atom with the gold foil experiment. He got the Nobel prize in chemistry in 1908.<\/span><\/p>\n<p> <\/p>\n                <\/div>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Use of \u03b1- Particle: Rutherford&#8217;s Gold Foil Experiment: <\/b><span style=\"font-weight: 400;\">In this experiment, fast moving <\/span><b>alpha (\u03b1)<\/b><span style=\"font-weight: 400;\">-particles were made to fall on a thin gold foil.\u00a0<\/span>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><b>Selection of Gold Foil: <\/b><span style=\"font-weight: 400;\">He selected a gold foil because he wanted as thin a layer as possible and this gold foil was about 1000 atoms thick.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><b>About \u03b1-particles: <\/b><span style=\"font-weight: 400;\">These particles are doubly-charged helium ions.\u00a0<\/span>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"3\"><span style=\"font-weight: 400;\">Since they have a <\/span><b>mass of 4u<\/b><span style=\"font-weight: 400;\">, the fast-moving \u03b1-particles have a considerable amount of energy.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><b>Deflection: <\/b><span style=\"font-weight: 400;\">It was expected that \u03b1-particles would be deflected by the subatomic particles in the gold atoms.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Deviated Result in Rutherford&#8217;s Alpha-Particle scattering experiment:<\/b><span style=\"font-weight: 400;\"> The \u03b1-particle scattering experiment gave totally unexpected results.\u00a0<\/span>\n<ul>\n<li><span style=\"font-weight: 400;\">Most of the fast moving \u03b1-particles passed straight through the gold foil.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">Some of the \u03b1-particles were deflected by the foil by small angles.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">One out of every 12000 particles appeared to rebound.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Observations: Atom&#8217;s Empty Spaces and Concentrated Positive Charge: <\/b><span style=\"font-weight: 400;\">Rutherford concluded from the \u03b1-particle scattering experiment that\u2013\u00a0<\/span>\n<ul>\n<li><span style=\"font-weight: 400;\">Most of the space inside the atom is empty because most of the \u03b1-particles passed through the<\/span><b> gold foil <\/b><span style=\"font-weight: 400;\">without getting deflected.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">Very few particles were deflected from their path, indicating that the positive charge of the atom occupies very little space.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">A very small fraction of \u03b1-particles were deflected by <\/span><b>18<\/b><b>0<\/b><b>0<\/b><b>,<\/b><span style=\"font-weight: 400;\"> indicating that all the positive charge and mass of the gold atom were concentrated in a very small volume within the atom.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<figure id=\"attachment_64239\" aria-describedby=\"caption-attachment-64239\" style=\"width: 391px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-64239\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/23-1.webp\" alt=\"Scattering \" width=\"391\" height=\"330\" srcset=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/23-1.webp 391w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/23-1-300x253.webp 300w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/23-1-360x304.webp 360w\" sizes=\"(max-width: 391px) 100vw, 391px\" \/><figcaption id=\"caption-attachment-64239\" class=\"wp-caption-text\">Scattering of \u03b1-particles by a gold foil<\/figcaption><\/figure>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Calculating Nucleus Radius:: <\/b><span style=\"font-weight: 400;\">He also calculated that the radius of the nucleus is about <\/span><b>1<\/b><b>0<\/b><b>5<\/b><b> times<\/b><span style=\"font-weight: 400;\"> less than the radius of the atom.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Nuclear Model of an Atom and the Central role of the nucleus: <\/b><span style=\"font-weight: 400;\">On the basis of his experiment, he put forward the <\/span><b>Nuclear Model of an Atom.<\/b>\n<ul>\n<li><span style=\"font-weight: 400;\">There is a positively charged centre in an atom called the <\/span><b>nucleus<\/b><span style=\"font-weight: 400;\">.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">Nearly all the mass of an atom resides in the nucleus.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">The electrons revolve around the nucleus in circular paths.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">The size of the nucleus is very small as compared to the size of the atom.\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Drawbacks of Rutherford\u2019s model: Stable Reality of Atoms:<\/b><span style=\"font-weight: 400;\"> The revolution of the electron in a circular orbit is not expected to be stable.\u00a0<\/span>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><span style=\"font-weight: 400;\">Any particle in a<\/span><b> circular orbit<\/b><span style=\"font-weight: 400;\"> would undergo acceleration and would radiate energy.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><span style=\"font-weight: 400;\">Thus, the revolving electron would lose energy and finally fall into the nucleus.\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"2\"><span style=\"font-weight: 400;\">If this were so, the atom should be <\/span><b>highly unstable<\/b><span style=\"font-weight: 400;\"> and hence matter would not exist in the form that we know.\u00a0<\/span>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"3\"><span style=\"font-weight: 400;\">Atoms are quite stable.<\/span><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n <div class=\"vc_gray_box\">\n                   <p> <\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-64240\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2.webp\" alt=\"Neils Bohr\" width=\"816\" height=\"1148\" srcset=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2.webp 816w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2-213x300.webp 213w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2-728x1024.webp 728w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2-768x1080.webp 768w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/image-2023-12-16T133123.544-2-360x506.webp 360w\" sizes=\"(max-width: 816px) 100vw, 816px\" \/><\/p>\n<p style=\"text-align: center;\"><b>Neils Bohr<\/b><\/p>\n<p><span style=\"font-weight: 400;\">He was born in Copenhagen on 7 October 1885. He was appointed professor of physics at Copenhagen University in 1916 and got the Nobel prize for his work on the structure of atom in 1922. Among Professor Bohr\u2019s numerous writings, three appearing as books are:\u00a0<\/span><\/p>\n<p><span style=\"font-weight: 400;\">(i) The Theory of Spectra and Atomic Constitution,\u00a0<\/span><\/p>\n<p><span style=\"font-weight: 400;\">(ii) Atomic Theory and,\u00a0<\/span><\/p>\n<p><span style=\"font-weight: 400;\">(iii) The Description of Nature.<\/span><\/p>\n<p> <\/p>\n                <\/div>\n<p>\u00a0<\/p>\n<h2><span style=\"font-size: 18pt;\"><b>How did Bohr reshape Atomic Structure with Discrete Electron Orbits and Energy Levels?<\/b><\/span><\/h2>\n<ul>\n<li><b>Overcoming Objections with Key Postulates: <\/b><span style=\"font-weight: 400;\">In order to overcome the objections raised against Rutherford\u2019s model of the atom, Neils Bohr put forward the following postulates:\u00a0<\/span>\n<ul>\n<li><span style=\"font-weight: 400;\">Only certain special orbits known as discrete orbits of electrons, are allowed inside the atom.\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">While revolving in discrete orbits the electrons do not radiate energy, a crucial aspect of atomic structure stability..\u00a0<\/span><\/li>\n<\/ul>\n<\/li>\n<li><span style=\"font-weight: 400;\">These orbits or shells are called <\/span><b>energy levels<\/b><span style=\"font-weight: 400;\"> .\u00a0<\/span><\/li>\n<li><span style=\"font-weight: 400;\">These orbits or shells are represented by the letters K,L,M,N,\u2026 or the numbers, n=1,2,3,4,\u2026., illustrating the hierarchical arrangement in the atomic structure.<\/span><\/li>\n<\/ul>\n<figure id=\"attachment_64243\" aria-describedby=\"caption-attachment-64243\" style=\"width: 377px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-64243\" src=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/63.webp\" alt=\"energy levels in an atom\" width=\"377\" height=\"239\" srcset=\"https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/63.webp 377w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/63-300x190.webp 300w, https:\/\/pwonlyias.com\/stage\/wp-content\/uploads\/2023\/12\/63-360x228.webp 360w\" sizes=\"(max-width: 377px) 100vw, 377px\" \/><figcaption id=\"caption-attachment-64243\" class=\"wp-caption-text\">A few energy levels in an atom<\/figcaption><\/figure>\n<h2><span style=\"font-size: 18pt;\"><b>J. Chadwick Neutron: Bridging the Mass Balance in Atomic Structure<\/b><\/span><\/h2>\n<ul>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Chadwick&#8217;s Neutron Discovery: Neutral Force in Atomic Structure: <\/b><span style=\"font-weight: 400;\">In 1932, J. Chadwick discovered another subatomic particle which had no charge and a mass nearly equal to that of a proton named as <\/span><b>neutron<\/b> <b>(represented as \u2018n\u2019)<\/b><span style=\"font-weight: 400;\">.<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Elemental Presence, Excluding Hydrogen: <\/b><span style=\"font-weight: 400;\">Neutrons are present in the nucleus of all atoms,<\/span><b> except hydrogen.<\/b><span style=\"font-weight: 400;\">\u00a0<\/span><\/li>\n<li style=\"font-weight: 400;\" aria-level=\"1\"><b>Mass Calculation in Atoms: <\/b><span style=\"font-weight: 400;\">The mass of an atom is therefore given by the sum of the masses of protons and neutrons present in the nucleus.<\/span><\/li>\n<\/ul>\n","protected":false},"featured_media":0,"parent":0,"template":"","notes-subjects":[4568],"subject-chapters":[4706],"acf":[],"_links":{"self":[{"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/ncert-notes\/64198"}],"collection":[{"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/ncert-notes"}],"about":[{"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/types\/ncert-notes"}],"wp:attachment":[{"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/media?parent=64198"}],"wp:term":[{"taxonomy":"notes-subjects","embeddable":true,"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/notes-subjects?post=64198"},{"taxonomy":"subject-chapters","embeddable":true,"href":"https:\/\/pwonlyias.com\/stage\/wp-json\/wp\/v2\/subject-chapters?post=64198"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}