Recently, the Union Minister for Power, inaugurated India’s first megawatt-hour (MWh) scale (VRFB) system at NTPC’s NETRA, Noida.
- VRFBs are one of the next generation battery technologies that offer critical advantages for grid-scale and renewable energy integration, supporting India’s transition towards sustainable power systems.
About Vanadium Redox Flow Battery (VRFB)
- Working Principle: VRFB is a type of flow battery where energy is stored in liquid electrolytes containing vanadium ions in different oxidation states.
- These electrolytes are circulated through cell stacks separated by an ion-selective membrane, which allows ions to pass while preventing mixing.
- The same element (vanadium) is used for both electrolytes, preventing cross-contamination and delivering a longer operational life.
- Advantages:
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- Scalability: Energy capacity depends on electrolyte volume, while power output is set by the cell stack size; both can be scaled independently.
- Safety: The water-based electrolyte is non-flammable, making the system safer than lithium-ion batteries.
- Longevity: Electrolyte can be reused or recycled, and the system can endure thousands of charge/discharge cycles without degradation.
- Full Discharge Tolerance: it can be fully discharged (100%) safely, unlike lithium-ion batteries, which risk damage if discharged completely.
- Eco-friendly: Reduced reliance on rare-earth and lithium imports, promoting indigenous solutions.
Vanadium Redox Flow Battery (VRFB) Vs. Lithium-Ion Battery
| Feature |
Vanadium Redox Flow Battery (VRFB) |
Lithium-Ion Battery |
| Energy Storage |
In liquid vanadium electrolytes |
In solid electrodes |
| Scalability |
Independent scaling (energy/power) |
Fixed cell capacity |
| Energy Density |
Lower, suitable for stationary use |
Higher, suitable for portable use |
| Safety |
Non-flammable, stable |
Can overheat, risk of fire |
| Lifespan |
>25 years, minimal degradation |
Loses capacity, ~5-10 years |
| Cost-effectiveness |
Higher upfront, lower over life |
Lower upfront, higher over life |
| Full discharge capacity |
100% discharge without damage |
Limited by chemistry, risk damage |
| Application |
Grid-scale, renewables, backup |
Vehicles, electronics, short-term storage |
Differences between Flow batteries and Solid-state batteries
| Feature |
Flow Battery |
Solid-State Battery |
| Key Working Principle |
Stores energy in external liquid electrolyte tanks; power and energy capacity are decoupled |
Uses solid electrolyte; energy and power density depend on compact cell design |
| Main Electrolyte |
Liquid electrolytes (usually vanadium or zinc-bromine solutions) |
Solid electrolyte (ceramic, glass, or polymer) |
| Scalability |
Easily scalable (increase tank size for more energy) |
Limited scalability; mostly modular for consumer/EV scales |
| Safety |
Lower thermal runaway risk; leakage possible |
Higher thermal stability; low risk of fire/explosion |
| Energy Density |
Lower (bigger, bulkier for same storage) |
Higher (compact and lightweight possible) |
| Typical Uses |
Grid storage, renewable energy integration |
Electric vehicles, portable electronics |
| Charge/Discharge Cycles |
Long cycle life, can withstand deep discharge |
Long cycle life, but depends on current technology |
| Commercial Examples |
– Vanadium Redox Flow (VRFB) (Sumitomo Electric, Invinity)
– Zinc-Bromine Flow (Redflow) |
– QuantumScape solid-state (for EVs)
– Toyota & Samsung advanced solid-sta |
About Vanadium
- Vanadium (symbol V, atomic number 23) is a transition metal found in the Earth’s crust.
- Properties:
- Hard, ductile, silvery-grey metal.
- It has a high melting point (~1910°C), excellent corrosion resistance.
- It forms compounds in multiple oxidation states (+2, +3, +4, +5), leading to vividly coloured complexes.
- Key in Vanadium Redox Flow Batteries (VRFBs): Vanadium’s ability to exist in several oxidation states enables efficient large-scale energy storage solutions.
- Industrial & Energy Uses:
- Steel Alloy: Primarily used to produce specialty steel alloys—adds strength, ductility, and resistance to corrosion.
- Aviation: Crucial for aerospace applications due to its strength-to-weight ratio.
- Catalyst in chemical industries: Notably in the production of sulphuric acid (vanadium pentoxide).
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Significance
- Strengthening Renewable Integration: Large-scale deployment of Vanadium Redox Flow Batteries (VRFBs), such as at NTPC NETRA, Noida, mitigates renewable energy intermittency, ensuring stable integration of solar and wind power into the national grid.
- Enhancing Energy Security and Sustainability: VRFBs diversify India’s energy storage portfolio, reduce dependence on imported lithium and rare earths, and set new benchmarks for safety and environmental sustainability.
- Boosting Technological Leadership: With growing domestic expertise in flow-battery systems, India is emerging as a global leader in long-duration energy storage (LDES) and clean energy innovation.