Vanadium Redox Flow Battery

12 Nov 2025

Vanadium Redox Flow Battery

Recently, the Union Minister for Power, inaugurated India’s first megawatt-hour (MWh) scale  (VRFB) system at NTPC’s NETRA, Noida. 

  • VRFBs are one of the next generation battery technologies that offer critical advantages for grid-scale and renewable energy integration, supporting India’s transition towards sustainable power systems.

About Vanadium Redox Flow Battery (VRFB)

  • Working Principle: VRFB is a type of flow battery where energy is stored in liquid electrolytes containing vanadium ions in different oxidation states. 
  • These electrolytes are circulated through cell stacks separated by an ion-selective membrane, which allows ions to pass while preventing mixing. 
  • The same element (vanadium) is used for both electrolytes, preventing cross-contamination and delivering a longer operational life.​
  • Advantages:
    • Scalability: Energy capacity depends on electrolyte volume, while power output is set by the cell stack size; both can be scaled independently.
    • Safety: The water-based electrolyte is non-flammable, making the system safer than lithium-ion batteries.
    • Longevity: Electrolyte can be reused or recycled, and the system can endure thousands of charge/discharge cycles without degradation.
    • Full Discharge Tolerance: it can be fully discharged (100%) safely, unlike lithium-ion batteries, which risk damage if discharged completely.
    • Eco-friendly: Reduced reliance on rare-earth and lithium imports, promoting indigenous solutions.​

Vanadium Redox Flow Battery (VRFB) Vs. Lithium-Ion Battery

Feature Vanadium Redox Flow Battery (VRFB) Lithium-Ion Battery
Energy Storage In liquid vanadium electrolytes In solid electrodes
Scalability Independent scaling (energy/power) Fixed cell capacity
Energy Density Lower, suitable for stationary use Higher, suitable for portable use
Safety Non-flammable, stable Can overheat, risk of fire
Lifespan >25 years, minimal degradation Loses capacity, ~5-10 years
Cost-effectiveness Higher upfront, lower over life Lower upfront, higher over life
Full discharge capacity 100% discharge without damage Limited by chemistry, risk damage
Application Grid-scale, renewables, backup Vehicles, electronics, short-term storage

Differences between Flow batteries and Solid-state batteries

Feature Flow Battery Solid-State Battery
Key Working Principle Stores energy in external liquid electrolyte tanks; power and energy capacity are decoupled Uses solid electrolyte; energy and power density depend on compact cell design
Main Electrolyte Liquid electrolytes (usually vanadium or zinc-bromine solutions) Solid electrolyte (ceramic, glass, or polymer)
Scalability Easily scalable (increase tank size for more energy) Limited scalability; mostly modular for consumer/EV scales
Safety Lower thermal runaway risk; leakage possible Higher thermal stability; low risk of fire/explosion
Energy Density Lower (bigger, bulkier for same storage) Higher (compact and lightweight possible)
Typical Uses Grid storage, renewable energy integration Electric vehicles, portable electronics
Charge/Discharge Cycles Long cycle life, can withstand deep discharge Long cycle life, but depends on current technology
Commercial Examples – Vanadium Redox Flow (VRFB) (Sumitomo Electric, Invinity)

– Zinc-Bromine Flow (Redflow)

– QuantumScape solid-state (for EVs)

– Toyota & Samsung advanced solid-sta

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About Vanadium

  • Vanadium (symbol V, atomic number 23) is a transition metal found in the Earth’s crust.
  • Properties:
    • Hard, ductile, silvery-grey metal.
    • It has a high melting point (~1910°C), excellent corrosion resistance.
    • It forms compounds in multiple oxidation states (+2, +3, +4, +5), leading to vividly coloured complexes.​
    • Key in Vanadium Redox Flow Batteries (VRFBs): Vanadium’s ability to exist in several oxidation states enables efficient large-scale energy storage solutions.​
  • Industrial & Energy Uses:
    • Steel Alloy: Primarily used to produce specialty steel alloys—adds strength, ductility, and resistance to corrosion.
    • Aviation: Crucial for aerospace applications due to its strength-to-weight ratio.
    • Catalyst in chemical industries:  Notably in the production of sulphuric acid (vanadium pentoxide).

Significance

  • Strengthening Renewable Integration: Large-scale deployment of Vanadium Redox Flow Batteries (VRFBs), such as at NTPC NETRA, Noida, mitigates renewable energy intermittency, ensuring stable integration of solar and wind power into the national grid.
  • Enhancing Energy Security and Sustainability: VRFBs diversify India’s energy storage portfolio, reduce dependence on imported lithium and rare earths, and set new benchmarks for safety and environmental sustainability.
  • Boosting Technological Leadership: With growing domestic expertise in flow-battery systems, India is emerging as a global leader in long-duration energy storage (LDES) and clean energy innovation.

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UDAAN PRELIMS WALLAH
Comprehensive coverage with a concise format
Integration of PYQ within the booklet
Designed as per recent trends of Prelims questions
हिंदी में भी उपलब्ध

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